Search results for "INFRARED DOUBLE-RESONANCE"
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Collisional Broadening of Rotational Lines in the Stimulated Raman Pentad Q-Branch of CD4
1992
Self- and argon-broadening coefficients are reported for a number of Raman Q-branch transitions in the nu(1) and nu(2) + nu(4) bands of (C-12)D4 at room temperature (296 K). The coefficients display a variation with j and with C exp n (symmetry species A, E, F) that is essentially independent of collision partner and which is similar to the j- and C exp n-dependence found in previous measurements of the IR line-broadening coefficients. The rotationally inelastic collision rates previously measured by Foy et al. (1988) for (C-13)D4 (V4 = 0, 1) in collision with (C-13)D4 or Ar account for only a part of the Raman broadening rate, suggesting possibly significant contributions to the linewidths…
Measurements of Collisional Line Widths in the Stimulated Raman Q-Branch of the v1 Band of Silane
1990
0377-0486; Self-broadened widths of 28SiH4 in the v1 Q-branch have been measured at room temperature (295 K) using high-resolution stimulated Raman spectroscopy. These collisional widths have been obtained by fitting a superposition of Voigt profiles to the experimental spectra in the pressure range 28-154 Torr. No evidence for line mixing within the tetrahedral components of a Q(J) line has been found. The line broadening coefficients for J up to 13 depend weakly on the rotational quantum number. The mean value is 103.7 x 10(-3) cm-1 atm-1.